A. Farhadi; S. Rostami; B. Ghobadian; Sh. Besharati
Abstract
Introduction Nowadays, due to higher environmental pollution and decreasing fossil fuels many countries make decisions to use renewable fuels and restrict using of fossil fuels. Renewable fuels generally produce from biological sources. Biodiesel is an alternative diesel fuel derived from the transesterification ...
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Introduction Nowadays, due to higher environmental pollution and decreasing fossil fuels many countries make decisions to use renewable fuels and restrict using of fossil fuels. Renewable fuels generally produce from biological sources. Biodiesel is an alternative diesel fuel derived from the transesterification of vegetable oils, animal fats, or waste frying oils. Considering the differences between diesel and biodiesel fuels, engine condition should be modified based on the fuel or fuel blends to achieve optimum performance. One of the simplest and yet the most widely used models is the thermodynamic model. After verification of the data obtained by model with experimental data it is possible to generalize the extracted data to an unlimited number of functional conditions or unlimited number of fuel types which saves time and reduces costs for experimental engine tests. Using the second law of thermodynamics, it is possible to calculate and analyze the exergy of the engine.4 Materials and Methods In this work, the zero-dimensional model was used to account for internal energy variations, pressure work, heat transfer losses to the solid walls and heat release. The applied assumptions include: The cylinder mixture temperature, pressure and composition were assumed uniform throughout the cylinder. Furthermore, the one-zone thermodynamic model assumes instantaneous mixing between the burned and unburned gases. The cylinder gases were assumed to behave as an ideal gas mixture, Gas properties, include enthalpy, internal energy modeled using polynomial equations associated with temperature. In this research, the equations 1 to 20 were used in Fortran programming language. The results of incylinder pressure obtained by the model were validated by the results of experimental test of OM314 engine. Then the effects of injection timing on Energy and Exergy of the engine were analyzed for B20 fuel. Results and Discussion Comparing the results of the model with the experimental data shows that there was a good agreement between the model and experimental results. The results showed that advancing fuel injection timing increases the peak cylinder pressure. When fuel injecting occurs before the standard injection timing, the pressure and temperature of the charged air in the cylinder is less than that of the fuel when it is injected at standard injection timing. Thus, ignition delay of the injected fuel extends further. As a consequence, the reaction between fuel and air improves, which prepares a good mixture for burning. When the combustion starts, the rate of heat release increases in the premixed or rapid combustion phase of the combustion process due to the suitability of the mixture of air and fuel and hence the peak pressure of cylinder increases. When the injection timing is retarded, the fuel is injected into charged air that has a high temperature and pressure. Thus, in the injection timing of 10 degrees before top dead center, the maximum of incylinder pressure and temperature are reduced compared to the standard injection timing. By retarding the fuel injection into the cylinder, the indicator availability, the heat loss availability by heat transfer from cylinder walls and irreversibility are increased and by advancing the fuel injection into the cylinder, the indicator availability, the heat loss availability by heat transfer from the cylinder walls and irreversibility are reduced. High temperature will increase the produced entropy, so by advancing the injection timing the produced entropy will increase while the retarding injection timing reduces the produced entropy. Exergy and energy efficiencies increased by advancing the injection timing. At 2000 rpm the total availability and heat loss availability by heat transfer was increased compared to 1200 and 1600 rpm. Conclusion The proposed model was able to predict the pressure and temperature of the cylinder at different injection timings. By advancing the fuel injection timing energy and exergy efficiency and heat loss availability by heat transfer was increased. At 2000 rpm the total availability and heat loss availability by heat transfer was increased.
B. Hosseinzdeh Samani; E. Fayyazi; B. Ghobadian; S. Rostami
Abstract
Introduction
Biodiesel is a promising renewable substitute source of fuel produced from tree born oils, vegetable based oils, fats of animals and even waste cooking oil, has been identified as one of the key solutions for the alarming global twin problems of fossil fuel depletion and environmental degradation. ...
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Introduction
Biodiesel is a promising renewable substitute source of fuel produced from tree born oils, vegetable based oils, fats of animals and even waste cooking oil, has been identified as one of the key solutions for the alarming global twin problems of fossil fuel depletion and environmental degradation. One of the sources for biodiesel production is mastic which is often grown in mountains. Its kernel contains 55% oil which makes it as a valuable renewable resource for biodiesel production. The objective of this research was to study of the feasibility of biodiesel production from Atlas mastic oil using ultrasonic system and optimization of the process using Response surface methodology.
Materials and Methods
In order to supply the required oil for the biodiesel production process, the oil should be prepared before the reaction. Hence, the purified oil was methylated using Metcalf et al (1996) method, and the prepared sample was injected into Gas Chromatography device to determine fatty acids profile and molecular weight of the used oil. An ultrasonic processor (Hielscher Model UP400S, USA.) was used to perform the transesterification reaction.
All the experiments were replicated three times to determine the variability of the results and to assess the experimental errors. The reported values are the average of the individual runs. The different operating parameters used in the present work, to optimize the extent of conversion of Atlas pistache oil, include methanol to oil molar ratio (4:1, 5:1 ,6:1), amplitude (24.1, 62.5 100%), pulse (24.1, 62.5 100%), reaction time (3, 6, 9 min).
Results and Discussion
Results of analyses showed that the independent variables, namely molar ratio, vibration amplitude, pulse and reaction time had significant effects on the amount of produced methyl ester.
By increasing the amplitude and pulse, the methyl ester content increased. Increase in amplitude and pulse cause to increase the mixing effect and physical interface. Increasing the ratio of ultrasonic working time to its idling time caused to an increase in the conversion percent. Because the treating time of the samples by ultrasound in limit time durations is increased, while this increase becomes lower at higher ratios. This is due to the fact that the initial vibrative shock acted on the samples after ultrasonic restarting, finds an identical effect with uniform wave. However, the idling phase of ultrasound caused a decrease in the amount of consumed energy. Similar results have been reported by Chand et al. (2010) for the effect of pulse on conversion percent of methyl ester. Trend of reaction time and molar ratio were different with trend of amplitude and molar ratio on methyl ester content so that they were divided to two sections. It should be mentioned that the increase in biodiesel yield because of molar ratio has some limitations. If the ratio is increased more than a certain extent, biodiesel conversion percent will decrease. The main reason for this result can be related to the amount of methanol increase in the mixture, which leads to more dissolution of glycerin and alcohol in biodiesel which considerably influences its purity.
Optimization was carried out based on Response Surface Methodology (RSM) using Design Experts software. The obtained results from optimization were as follow: 5.45 molar ratio, 0.89 amplitude, 0.71 pulse and 5.99 minutes of time. The conversion percentage obtained as 94.96. It is worthy to note that the experiment was iterated at suggested point by the optimization software and the conversion percent was 94.02. As well as 34792.37 J at the obtained point to be acceptable (1%) difference from the model.
Conclusions
The increase in the ultrasound amplitude resulted in an increase in the conversion percentage which tends to ascend. Also, the increase of reaction time by 5 to 7 minutes increased the conversion percentage, following which is the descend trend. The obtained results from optimization were as follow: 5.45 molar ratio, 0.89 amplitude, 0.71 pulse and 5.99 minutes of time. The conversion percentage and consumed energy obtained as 94.96 and 32421.5 J, respectively. It is worthy to note that the experiment was iterated at suggested point by the optimization software and the conversion percent was 94.02.
