Bioenergy
J. Rezaeifar; A. Rohani; M. A. Ebrahimi-Nik
Abstract
In the quest for enhanced anaerobic digestion (AD) performance and stability, iron-based additives as micro-nutrients and drinking water treatment sludge (DWTS) emerge as key players. This study investigates the kinetics of methane production during AD of dairy manure, incorporating varying concentrations ...
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In the quest for enhanced anaerobic digestion (AD) performance and stability, iron-based additives as micro-nutrients and drinking water treatment sludge (DWTS) emerge as key players. This study investigates the kinetics of methane production during AD of dairy manure, incorporating varying concentrations of Fe and Fe3O4 (10, 20, and 30 mg L-1) and DWTS (6, 12, and 18 mg L-1). Leveraging an extensive library of non-linear regression (NLR) models, 26 candidates were scrutinized and eight emerged as robust predictors for the entire methane production process. The Michaelis-Menten model stood out as the superior choice, unraveling the kinetics of dairy manure AD with the specified additives. Fascinatingly, the findings revealed that different levels of DWTS showcased the highest methane production, while Fe3O420 and Fe3O430 recorded the lowest levels. Notably, DWTS6 demonstrated approximately 34% and 42% higher methane production compared to Fe20 and Fe3O430, respectively, establishing it as the most effective treatment. Additionally, DWTS12 exhibited the highest rate of methane production, reaching an impressive 147.6 cc on the 6th day. Emphasizing the practical implications, this research underscores the applicability of the proposed model for analyzing other parameters and optimizing AD performance. By delving into the potential of iron-based additives and DWTS, this study opens doors to revolutionizing methane production from dairy manure and advancing sustainable waste management practices.
Bioenergy
M. Zarei; M. R. Bayati; M. A. Ebrahimi-Nik; B. Hejazi; A. Rohani
Abstract
IntroductionAnaerobic bacteria break down organic materials like animal manure, household trash, plant wastes, and sewage sludge during the anaerobic digestion process of biological materials and produce biogas. One of the main issues in using biogas is hydrogen sulfide (H2S), which can corrode pipelines ...
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IntroductionAnaerobic bacteria break down organic materials like animal manure, household trash, plant wastes, and sewage sludge during the anaerobic digestion process of biological materials and produce biogas. One of the main issues in using biogas is hydrogen sulfide (H2S), which can corrode pipelines and engines in concentrations between 50 and 10,000 ppm. One method for removing H2S from biogas with minimal investment and operation costs is biofiltration. Whether organic or inorganic, the biofilter's bed filling materials must adhere to certain standards including high contact surface area, high permeability, and high absorption. In this study, biochar and compost were used as bed particles in the biofilter to study the removal of H2S from the biogas flow in the lab. Afterward, kinetic modeling was used to describe the removal process numerically.Material and MethodsTo remove H2S from the biogas, a lab-sized biofilter was constructed. Biochar and compost were employed separately as the material for the biofilter bed. Because of its high absorption capacity and porosity, biochar is a good choice for substrate and packed beds in biofilters. The biochar pieces used were broken into 10 mm long cylindrical pieces with a diameter of 5 mm. Compost was used as substrate particles because it contains nutrients for microorganisms. Compost granules with an average length of 7.5 mm and 3 mm in diameter were used in this study. For the biofilter reactor, each of these substrates was put inside a cylinder with a diameter of 6 cm and a height of 60 cm. The biofilter's bottom is where the biogas enters, and its top is where it exits. During the experiment, biogas flowed at a rate of 72 liters per hour. Mathematical modeling was used to conduct kinetic studies of the process to better comprehend and generalize the results. This method involves feeding the biofilter column with biogas that contains H2S while the biofilm is present on the surface of the biofilter bed particles. The bacteria in the biofilm change the gaseous H2S into the harmless substance sulfur and store it in their cells. The assumptions that form the foundation of the mathematical models are: the H2S concentration is uniform throughout the gas flow, the gas flow is constant, and the column's temperature is constant at a specific height.Results and DiscussionIn the beginning, biochar was used as a substrate in the biofilter to test its effectiveness, and the results obtained for removing H2S from the biogas were acceptable. H2S concentration in biogas was significantly reduced using biochar beds. It dropped from 300 ppm and 200 ppm to 50 ppm where the greatest H2S concentration reduction was achieved. The level of Methane in the biogas was not significantly impacted by the biofilter. This is regarded as a significant outcome when taking into account the goal which is producing biogas with a high concentration of methane. The H2S elimination effectiveness was 94% with the biochar bed and biogas input with 185 ppm H2S concentration. The removal efficiency reached 76% with the compost bed and input concentration of 70 ppm. Using mathematical models, the simulation was carried out by modifying the model's parameters until the predicted results closely matched the experimental data. It may be concluded that the suggested mathematical model is sufficient for the quantitative description of H2S removal from biogas utilizing biofilm in light of how closely the calculation results matched the experimental data. The only model parameter that was changed to make the model results almost identical to the experimental data was the value of the maximum specific growth rate (μmax) which has the greatest influence on the model results. The value of μmax for the biochar bed was calculated as 0.0000650 s-1 and for the compost bed at 70 ppm and 35 ppm concentrations as 0.0000071 s-1 and 0.0000035 s-1, respectively.ConclusionThe primary objective of this study is to examine the removal of H2S from biogas using readily available and natural substrates. According to the findings, at a height of 60 cm, H2S concentration in biochar and compost beds decreased from 185 ppm to 11 ppm (removal efficiency: 94%) and from 70 ppm to 17 ppm (removal efficiency: 76%), respectively. The mathematical models that were created can quantify the H2S elimination process, and the μmax values in biochar and compost were calculated as 0.0000650 s-1 and 0.0000052 s-1, respectively.AcknowledgmentThe authors would also like to thank UNESCO for providing some of the instruments used in this study under grant number No. 18-419 RG, funded by the World Academy of Sciences (TWAS).
Design and Construction
M. A. Ebrahimi-Nik; A. Rohani
Abstract
Introduction More than 40 percent of the world population is now dependent on biomass as their main source of energy for cooking. In Iran, the lack of access roads and inefficient transportation structure have made some societies to adopt biomass as the main energy source for cooking. In such societies, ...
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Introduction More than 40 percent of the world population is now dependent on biomass as their main source of energy for cooking. In Iran, the lack of access roads and inefficient transportation structure have made some societies to adopt biomass as the main energy source for cooking. In such societies, inefficient traditional three-wall cook stoves (TCS) are the sole method of cooking with biomass, which corresponds to the large fuel consumption and smoke emission. Biomass gasifier cook stoves have been on the focus of many studies as a solution for such regions. In these stoves, biomass is pyrolized with the supply of primary air. The pyrolysis vapors are then mixed with secondary air in a combustion chamber where a clean flame forms. In this study, a biomass cook stove was manufactured and its performance was evaluated feeding with three kind of biomass wastes (e.g. almond shell, wood chips, and corn cob). Materials and Methods A natural draft semi-gasifier stove was manufactured based on the stove proposed by (Anderson et al., 2007). It had two concentric metal cylinders with two sets of primary and secondary air inlet holes. It had 305 mm height and 200 mm diameter. The stove was fed by wood chips, almond shell, and corn cob. Thermal performance of the stove was evaluated based on the standard for water boiling test. It consisted of three phases of cold start, hot start, and simmering. Time to boil, burning rate, and fire power was measured in minute. A “K” type thermocouple was used to measure the water temperature. Emission of carbon monoxide from the stove was measured in three situations (e.g. open area, kitchen without hood, and kitchen under hood) using CO meter (CO110, Thaiwan). Results and Discussion Neither particulate matter nor smoke was visually observed during the stove operation except at the final seconds when the stove was going to run out of fuel. The flame color was yellow and partly blue. The average time to boil was 15 min; not significantly longer than that of the LPG stove (13 min). Time to boil in hot phase was almost the same for all fuels which is not in line with the studies reported by (Kshirsagar and Kalamkar, 2014; Ochieng et al., 2013; Parmigiani et al., 2014). This is probably due to the stove body material. In fact, the hot phase test, aims to show the effect of the stove body temperature on the performance. In contrast with the most of the stoves, the one was used in the present study was made of a thin (0.3 mm) iron sheet which has a high heat transfer and low heat capacity. This results in a rapid increase in the stove body temperature up to its highest possible. The longest flaming duration (51 min) was observed by 350 g almond shell. Thermal efficiency on the other hand, was different in using different biomass fuels. The average thermal efficiency of 40.8 was achieved by the stove which is almost three times of open fire. The results from emission test showed that the average of carbon monoxide surrounding the operator in the case of open area, kitchen without hood, kitchen under hood, and traditional open fire were 4.7, 7.5, 5.2, and 430 ppm, respectively. Conclusion The amount of carbon monoxide emitted to the room is in accordance with the US National ambient air quality standards (NAAQS) hence, compared with traditional methods of cooking in deprived regions, the stove burns cleaner with higher efficiency. In order to prohibit respiratory decreases in housekeeping women, this stove could be disseminated in some deprived regions of Iran.
M. A. Ebrahimi-Nik; A. Heidari; H. Younesi
Abstract
Fast pyrolysis is an attractive technology for biomass conversion, from which bio-oil is the preferred product with a great potential for use in industry and transport. Corn wastes (cob and stover) and eucalyptus wood are widely being produced throughout the world. In this study, fast pyrolysis of these ...
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Fast pyrolysis is an attractive technology for biomass conversion, from which bio-oil is the preferred product with a great potential for use in industry and transport. Corn wastes (cob and stover) and eucalyptus wood are widely being produced throughout the world. In this study, fast pyrolysis of these two materials were examined under the temperature of 500 °C; career gas flow rate of 660 l h-1; particle size of 1-2 mm; 80 and 110 g h-1 of feed rate. The experiments were carried out in a continuous fluidized bed reactor. Pyrolysis vapor was condensed in 3 cooling traps (15, 0 and -40 °C) plus an electrostatic one. Eucalyptus wood was pyrolyised to 12.4, 61.4, and 26.2 percent of bio-char, bio-oil and gas, respectively while these figures were as 20.15, 49.9, and 29.95 for corn wastes. In all experiments, the bio-oil obtained from electrostatic trap was a dark brown and highly viscose liquid.
