Bioenergy
M. Zarei; M. R. Bayati; M. A. Ebrahimi-Nik; B. Hejazi; A. Rohani
Abstract
IntroductionAnaerobic bacteria break down organic materials like animal manure, household trash, plant wastes, and sewage sludge during the anaerobic digestion process of biological materials and produce biogas. One of the main issues in using biogas is hydrogen sulfide (H2S), which can corrode pipelines ...
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IntroductionAnaerobic bacteria break down organic materials like animal manure, household trash, plant wastes, and sewage sludge during the anaerobic digestion process of biological materials and produce biogas. One of the main issues in using biogas is hydrogen sulfide (H2S), which can corrode pipelines and engines in concentrations between 50 and 10,000 ppm. One method for removing H2S from biogas with minimal investment and operation costs is biofiltration. Whether organic or inorganic, the biofilter's bed filling materials must adhere to certain standards including high contact surface area, high permeability, and high absorption. In this study, biochar and compost were used as bed particles in the biofilter to study the removal of H2S from the biogas flow in the lab. Afterward, kinetic modeling was used to describe the removal process numerically.Material and MethodsTo remove H2S from the biogas, a lab-sized biofilter was constructed. Biochar and compost were employed separately as the material for the biofilter bed. Because of its high absorption capacity and porosity, biochar is a good choice for substrate and packed beds in biofilters. The biochar pieces used were broken into 10 mm long cylindrical pieces with a diameter of 5 mm. Compost was used as substrate particles because it contains nutrients for microorganisms. Compost granules with an average length of 7.5 mm and 3 mm in diameter were used in this study. For the biofilter reactor, each of these substrates was put inside a cylinder with a diameter of 6 cm and a height of 60 cm. The biofilter's bottom is where the biogas enters, and its top is where it exits. During the experiment, biogas flowed at a rate of 72 liters per hour. Mathematical modeling was used to conduct kinetic studies of the process to better comprehend and generalize the results. This method involves feeding the biofilter column with biogas that contains H2S while the biofilm is present on the surface of the biofilter bed particles. The bacteria in the biofilm change the gaseous H2S into the harmless substance sulfur and store it in their cells. The assumptions that form the foundation of the mathematical models are: the H2S concentration is uniform throughout the gas flow, the gas flow is constant, and the column's temperature is constant at a specific height.Results and DiscussionIn the beginning, biochar was used as a substrate in the biofilter to test its effectiveness, and the results obtained for removing H2S from the biogas were acceptable. H2S concentration in biogas was significantly reduced using biochar beds. It dropped from 300 ppm and 200 ppm to 50 ppm where the greatest H2S concentration reduction was achieved. The level of Methane in the biogas was not significantly impacted by the biofilter. This is regarded as a significant outcome when taking into account the goal which is producing biogas with a high concentration of methane. The H2S elimination effectiveness was 94% with the biochar bed and biogas input with 185 ppm H2S concentration. The removal efficiency reached 76% with the compost bed and input concentration of 70 ppm. Using mathematical models, the simulation was carried out by modifying the model's parameters until the predicted results closely matched the experimental data. It may be concluded that the suggested mathematical model is sufficient for the quantitative description of H2S removal from biogas utilizing biofilm in light of how closely the calculation results matched the experimental data. The only model parameter that was changed to make the model results almost identical to the experimental data was the value of the maximum specific growth rate (μmax) which has the greatest influence on the model results. The value of μmax for the biochar bed was calculated as 0.0000650 s-1 and for the compost bed at 70 ppm and 35 ppm concentrations as 0.0000071 s-1 and 0.0000035 s-1, respectively.ConclusionThe primary objective of this study is to examine the removal of H2S from biogas using readily available and natural substrates. According to the findings, at a height of 60 cm, H2S concentration in biochar and compost beds decreased from 185 ppm to 11 ppm (removal efficiency: 94%) and from 70 ppm to 17 ppm (removal efficiency: 76%), respectively. The mathematical models that were created can quantify the H2S elimination process, and the μmax values in biochar and compost were calculated as 0.0000650 s-1 and 0.0000052 s-1, respectively.AcknowledgmentThe authors would also like to thank UNESCO for providing some of the instruments used in this study under grant number No. 18-419 RG, funded by the World Academy of Sciences (TWAS).
S. Mollazehi; H. Sadrnia; M. R. Bayati
Abstract
Introduction In recent decays, the microwave heating treatment is one of the best ways for the pest control. It is difficult to determine temperature in different parts of materials by Thermometer, but we can solve this problem by Comsol Multiphysics Software. In a research, results of a farm test were ...
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Introduction In recent decays, the microwave heating treatment is one of the best ways for the pest control. It is difficult to determine temperature in different parts of materials by Thermometer, but we can solve this problem by Comsol Multiphysics Software. In a research, results of a farm test were consistent with laboratory data and high temperature area was belonged to the outer part of wooden piece (Massa et al., 2015). The numerical simulation of Microwave heating was successfully done for fruits and compared with experimental measurement in two cylindrically and spherically states by Zhao et al. (2011). The results indicated that, the temperature prediction in a wooden piece under heating of a Microwave system was in conformity with experimental infra-red rays data (Rattanadecho, 2006). The outer part of the piece was impressed by inspired heating and the inner part by transmission of heating (Massa et al., 2011). A high frequency structure simulator software, a radiant trumpet shaped antenna with 2.45GHz frequencies, 100 watt electric power were the tools that were used to predict the temperature at a Date Palm Wooden piece at 10, 12, 14 and 16 centimeters (Al Shwear and Remili, 2016). Microwave pretreatment was studied with two factors of Microwave radiation (170, 450, and 850 W) and Microwave duration (2, 6, and 10 min). It can be concluded that the Ozonolysis is the most effective pretreatment regarding to saccharification percentage of sugarcane bagasse (Eqra et al., 2015). This study has been done with the aim of fighting with Rhynchophorus ferrugineus blight by microwave and removing toxins in crops. Materials and Methods Samples features such as physical, mechanical and magnetic once were established in both Tehrans Material and Energy lab and Polymer and Petrochemical Research Center, Then it was simulated by Time_ Temperature profile software. For simulating research by Comsol Multiphysics software, at first sample and chamber sizes were determined and the type of material, meshing, 2.45GHz frequencies and the time duration of heating were measured, respectively. Finally the research was analyzed and Time_Temperature profile which was one of the outcomes of Multiphysics software was determined. A cubic piece of wood (103×86×78 mm) (Fig. 1), a Digital Thermometer and a Microwave are the tools which the researcher used in this sample. The temperature was measured at three different parts of cub diagonal by Thermometer. At first, the wooden sample was divided in two equal parts and a sensor was placed in the middle of it and then it was placed in the Microwave. The primary temperature of sample and Microwaves was 27°C. We turn the Microwave on for a period of 10 minutes, after that we check the wooden piece temperature by Thermometer at 20 seconds intervals. Results and Discussion T-test was used to compare statistical results achieved by simulated and experimental temperature of cubic diagonal. According to T mark at 5 percent level, we can say that there is a significant difference between simulated and experimental temperature at point1, however, there is no such a significant difference at 2 and 3 points. In the following phase, the temperature was compared at two simulated and experimental states by variance analysis test. There was significant difference at 1, 2 and 3 points according to data are shown at figure 4. Moreover, Duncan Post hoc test is shown at figures 5 and 7 that experimental temperature shows no difference at 1 and 3 points but it makes difference at 1, 2 and 2, 3 points. Conclusion Results show that the simulation model can predict the temperature in different parts of a wooden sample. The temperature will be higher as much as the points will be closer to the wave producer resource. In order to control pests in the trunk of a tree, we should use several wave generator systems, instead of ones. It is recommended that cylindrical microwave should be simulated and designed instead cubic ones, because it is better adjusted with tree stock and the wave generator system is placed on this surface so that the temperature will be distributed symmetrically along the diagonal.
M. R. Bayati; A. Rajabipour; H. Mobli; A. Eyvani; F. Badii
Abstract
Introduction: Apple fruit (Mauls domestica Borkh, Rosaceae) after citrus fruits, grape and banana, is the fourth important fruit in the world and is considered the most important fruit of temperate regions. In terms of trade volume, Iran is fourth producer and 17th exporter in the world. Among Iranian ...
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Introduction: Apple fruit (Mauls domestica Borkh, Rosaceae) after citrus fruits, grape and banana, is the fourth important fruit in the world and is considered the most important fruit of temperate regions. In terms of trade volume, Iran is fourth producer and 17th exporter in the world. Among Iranian cultivars of apple fruit, known as “Golab apple”. Golab apple is one of the fragrant and tasty varieties and meanwhile is very sensitive and also its period of the postharvest shelf life is very short. In a study, the firmness of pear fruit during 4 weeks of storage was monitored using non-destructive impulse response (I-R) and destructive Magness-Taylor (M-T) puncture tests. The results of this study showed that the dominant frequency, stiffness coefficient and elasticity coefficient as a function of time could be expressed as a decreasing linear function (Gómez et al., 2005). Tiplica et al., (2010), showed that acoustic measurement can be a useful tool to discriminate different apple batches with a low error rate. Starting from the spectrum of the signal recorded by a microphone after the impact of a small hammer on the fruit, 18 key features were identified and used for the classification of apples belonging to 10 different varieties. The study aimed to evaluate apple firmness measured using both the penetrometer and acoustic methods. The methodologies were applied to Royal Gaya and Golden Smoothee apples harvested from 12 different orchards in Catalonia (Spain), on six different dates, and over three seasons. The results obtained showed a noticeable correlation between Magness Taylor firmness and acoustic measurements in Royal Gala, but no correlation was found for Golden Smoothee. In this study, also, acoustic measurements seemed to be a good tool for evaluating changes in tissue firmness during long-term storage (Molina-Delgado et al., 2009). In another study, it was presented a novel approach based on the simultaneous profiling of the mechanical and acoustic response of the flesh tissue to compression, using a texture analyzer coupled with an acoustic device. The methodology was applied to a 86 different apple cultivars, measured after two months postharvest cold storage and characterised by 16 acoustic and mechanical parameters. The results demonstrate the good performance of our combined acoustic-mechanical strategy in measuring apple crispness as it is perceived by human senses (costa et al, 2011). Hence, present study was about postharvest durability evaluation of this apple in cold storage and effect of methylcellulose coating on durability of this sensitive apple for both intact and damaged ones.
Materials and Methods: After obtaining Golab apples, from one of the gardens of Karaj (Alborz province, Iran), 240 of them were selected. Our aim in this study was to evaluate the firmness of apples with two methods: penetration (destructive) and acoustic (non destructive). The tests were performed in Agricultural Engineering Research Institute in Karaj. Firmness is one of the fruit characteristics that changes during storage. In present study, this characteristic of the apple fruit was assessed by two mentioned methods. Half of the apples were damaged with identified and controlled impact. In the next stage, another half of apples in both groups (the intact apples and the bruised apples) were coated with methylcellulose. Effect storage on apple in four groups, including: Intact and uncoated apples, intact and coated (with methylcellulose) apples, bruised and uncoated apples and bruised and coated apples during about ten weeks of cold storage at 2˚C and 85% RH was studied by the acoustic and the penetration tests. Acoustic parameters including: natural frequency, firmness index, elasticity coefficient were measured by recording audio signals resulting from non destructive impacts of a pendulum using a sound analyzer microphone and then the conversion of those parameters were performed from the time domain to the frequency domain by the corresponding formulas and software. Penetration test measurements were performed using a texture analyzer and its software. The tests were carried out every week. Statistical analysis of the results was carried out using Excel 2007 and SPSS 16 software and the significance of the results was determined using Duncan's test at the 5% confidence level.
Results and Discussion: Analysis of variance showed effect of independent variables including: effects of coating, impact and time and also interaction effects on dependent variables including: natural frequency, acoustic index and modulus of elasticity and penetration index on the tested apples. Effects of coating and time were significant at the 5% confidence levelon all dependent variables. But the impact and interaction effect were not significant on dependent variables (Table 1). In general, bruise and lack of coating on the apples during the 10 weeks of storage, were reduced acoustic parameters. In the penetration test, changes were similar to acoustic test (Table 2). In this test, all curves have downward trend and combination of independent variables: coated and intact apples were reasons of more penetration resistance of apples in all of the groups. The condition was continued until the end of storage time, despite of the downwards slopped curves in all groups. In penetration test, coated apples keep more firmness than other groups (groups of apples without coating) and thus the apple's quality would stay better, too (Fig.7).
Conclusions: In general, the following results were obtained from this research: The results showed that the acoustic and penetration parameter were decreased during 10 weeks of storage. Reduction of these parameters continued until the end of storage period, but this reduction was significant only up to eighth week. Also at this time, the acoustic parameters (natural frequency, firmness index, elasticity coefficient) and penetration firmness in intact and coated apples were 14.26%, 4.11%, 14% and 40% respectively higher compared to other apples. Due to the more tangible acoustic parameters changes, especially acoustic index and modulus of elasticity (having the more slope than the penetration firmness). One could use acoustic tests for more accurate evaluation of apples firmness and quality changes. Finding correlation between acoustic parameters and penetration parameter showed that, correlation between acoustic parameters in each case is greater than correlation between these parameters with penetration parameter.
M. H. Aghkhani; M. H. Abbaspour-Fard; M. R. Bayati; H. Mortezapour; S. I. Saedi; A. Moghimi
Abstract
Drying is a high energy consuming process. Solar drying is one of the most popular methods for dehydration of agricultural products. In the present study, the performance of a forced convection solar dryer equipped with recycling air system and desiccant chamber was investigated. The solar dryer is comprised ...
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Drying is a high energy consuming process. Solar drying is one of the most popular methods for dehydration of agricultural products. In the present study, the performance of a forced convection solar dryer equipped with recycling air system and desiccant chamber was investigated. The solar dryer is comprised of solar collector, drying chamber, silica jell desiccant chamber, air ducts, fan and measuring and controlling system. Drying rate and energy consumption in three levels of air temperature (40, 45 and 50 oC) and two modes of drying (with recycling air and no-recycling with open duct system) were measured and compared. The results showed that increasing the drying air temperature decreased the drying time and increased the energy consumption in the mode of non-recycling air system. The dryer efficiency and drying rate were better in the mode of recycling air system than open duct system. The highest dryer efficiency was obtained from drying air temperature of 50 oC and the mode of recycling air system. In general, the efficiency of solar collector and the highest efficiency of the dryer were 0.34 and 0.41, respectively.
